I never knew this existed, so I can't tell you how excited I was to find this.
"Tom Waits For No One" is an Academy Award winning short (for Scientific & Technical Achievement), with Waits singing "The One That Got Away" from his Small Change album. The footage got rotoscoped and was designed to be one of the first videos to go on the barely fledging MTV. Things led to other things and it never happened, but here it is now. Said it before, say it again - God bless YouTube.